| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 10571719 | Inorganica Chimica Acta | 2005 | 11 Pages |
Abstract
We report on the ligand exchange reaction of [Et4N][Re2(CO)6(OR)3] with substituted aryl alcohols and with ethylene glycol. Complete exchange is fast with the alkyl alcohol but for the aryl alcohols exchange is facile only for two substitutions, the third substitution can be forced by raising the reaction temperature. X-ray crystal determinations were carried out for several of the derivatives.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
![Synthesis, characterization and X-ray structure of several aryloxide and alkoxide derivatives of [Et4N][Re2(CO)6(OR)3] (RÂ =Â H or Me)](/preview/png/10571719.png "First Page Preview: Synthesis, characterization and X-ray structure of several aryloxide and alkoxide derivatives of [Et4N][Re2(CO)6(OR)3] (RÂ =Â H or Me)")
Authors
Kevin K. Klausmeyer, Franklin R. Beckles,