| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 10571725 | Inorganica Chimica Acta | 2005 | 7 Pages |
Abstract
The Cu(I) complexes [Cu(btmgp)I] and [Cu2(btmgp)2][PF6]2 react with O2 to form binuclear bis(μ-oxo)copper(III) complexes at low temperatures; these species convert to bis(μ-alkoxo)dicopper(II) and bis(μ-hydroxo)dicopper(II) complex cations in a 1:1 ratio on warming up to room temperature.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
![Hydroxylation of a methyl group: synthesis of [Cu2(btmmO)2I]+ and of [Cu2(btmmO)2]2+ containing the novel ligand {bis(trimethylmethoxy)guanidino}propane (btmmO) by copper-assisted oxygen activation](/preview/png/10571725.png "First Page Preview: Hydroxylation of a methyl group: synthesis of [Cu2(btmmO)2I]+ and of [Cu2(btmmO)2]2+ containing the novel ligand {bis(trimethylmethoxy)guanidino}propane (btmmO) by copper-assisted oxygen activation")
Authors
Sonja Herres, Andreas J. Heuwing, Ulrich Flörke, Jörg Schneider, Gerald Henkel,