Article ID Journal Published Year Pages File Type
10571740 Inorganica Chimica Acta 2005 7 Pages PDF
Abstract
Four complexes of AgCN with alkanediamine ligands, in N,N′-bis(ethane-1,2-diamine)cyanosilver(I) (1), N,N′-bis(propane-1,2-diamine)cyanosilver(I) (2), μ-(propane-1,3-diamine)di[cyanosilver(I)] (3) and μ-(butane-1,4-diamine)di[cyanosilver(I)] (4), have been synthesised and structurally characterised. In these species, alkanediamine ligands act both as chelating (1 and 2) and bridging ligands (3 and 4). The different stoichiometries in the products have been obtained by varying preparation methods, solvents and AgCN to alkanediamine ratios.
Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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