| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 10571744 | Inorganica Chimica Acta | 2005 | 13 Pages |
Abstract
Diiron and diruthenium aminocarbyne complexes containing pseudohalide ligands (i.e., NCSâ, NCOâ, N3â) have been obtained by nitrile replacement; both cis and trans isomers can be formed depending on the reaction temperature and trans to cis isomerisation is observed at high temperature. The terminal azido ligand undergoes 1,3-dipolar cycloaddition reactions with alkynes and fumaronitrile, affording new dinuclear triazolato complexes.
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Authors
Luigi Busetto, Fabio Marchetti, Stefano Zacchini, Valerio Zanotti,