Article ID Journal Published Year Pages File Type
10571759 Inorganica Chimica Acta 2005 5 Pages PDF
Abstract
The facile reaction of [CpCr(CO)3]2 (Cp = η5-C5H5) (1) with Bz2S3 was postulated to proceed via a 17-electron radical pathway at ambient temperature to give [CpCr(CO)2]2S (3) and [CpCr(CO)2(SBz)]2 (4) as primary products. Thermolytic studies at 80 °C showed the degradation of 4-3 and [CpCr(SBz)]2S (5). Further prolonged thermolysis of 3-5 eventually gave Cp4Cr4S4 (6).
Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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