Article ID Journal Published Year Pages File Type
10571761 Inorganica Chimica Acta 2005 5 Pages PDF
Abstract
Polymeric, dimeric, and monomeric carboxylato zinc(II) cyclams have been synthesized and structurally characterized by a combination of analytical, spectroscopic and crystallographic methods. The carboxylato ligands in all the complexes show strong coordination tendencies toward zinc(II) cyclams with hydrogen bonding interactions between the pre-organized N-H groups of the macrocycle and oxygen atoms of the carboxylato ligands. The finding of strong interactions between the carboxylato ligands and the zinc(II) ions may provide additional knowledge for the improved design of receptor-targeted zinc(II) cyclams in anti-HIV agents.
Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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