Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
10571765 | Inorganica Chimica Acta | 2005 | 4 Pages |
Abstract
Crystallographic and magnetic studies have been performed on the complex, [{CuCl}2(μ-tppz)][PF6]2, where tppz is 2,3,5,6-tetra-2-pyridinylpyrazine. The crystal structure revealed an infinite, ionic chain. The temperature-dependent magnetic susceptibilitity could be satisfactorily fitted by using a modified Bleaney-Bowers expression (for H = âJSa · SbJ = â5.6 cmâ1 and g = 2.16) where the exchange interaction is suggested to involve the orbitals of the tppz ligand.
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Hassan Hadadzadeh, Ali R. Rezvani, Glenn P.A. Yap, Robert J. Crutchley,