Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
10571830 | Inorganica Chimica Acta | 2011 | 7 Pages |
Abstract
⺠The four step syntheses of a new N6 donor set ligand, dimpyen is devised. ⺠The reaction with Fe(II) gives off a novelheptacoordinated iron(III) complex. ⺠Magnetic studiesconfirm a high-spin iron (III) species in all the temperature range considered. ⺠Cyclic voltammetry confirm a reversible system Fe(III) species, with a very low redox potential. ⺠The change of the metal ion oxidation state can be explained in terms of the redox properties of the system.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Norma Ortega-Villar, VÃctor M. Ugalde-SaldÃvar, Blas Flores-Pérez, Marcos Flores-Alamo, J.A. Real, Rafael Moreno-Esparza,