| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 10571833 | Inorganica Chimica Acta | 2011 | 8 Pages |
Abstract
⺠Platinum(II) complexes of camphanylphosphonic acid (CamPO3H2) prepared by one-pot synthesis. ⺠NMR reveals inequivalent phosphines for PPh3 and dppe complexes, but equivalent for PPhMe2. ⺠X-ray structure on [Pt(O3PCam)(PPh3)2] shows Cam group pointing into pocket formed by PPh3 ligands. ⺠Differences in fluxional behaviour rationalised by theoretical study. ⺠X-ray structure of CamPO3H2 shows H-bonded hexamer, with organic sheath around hydrophilic core.
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Meto T. Leach, William Henderson, Alistair L. Wilkins, Joseph R. Lane, Ryland G. Fortney-Zirker, Mark M. Turnbull, Brian K. Nicholson,