| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 10571860 | Inorganica Chimica Acta | 2011 | 5 Pages |
Abstract
⺠A chiral SCO complex fac-Î-[FeII(HLR)3](ClO4)2·EtOH was synthesized. ⺠The crystal structures at the high-spin and low-spin states were determined. ⺠The complex exists as the facial-Î-isomer of fac-Î-[FeII(HLR)3]2+. ⺠The R-form of the ligand induces the fac-Î-isomer. ⺠The complex shows a complete SCO between the HS and LS states at T1/2 = 195 K.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
2·EtOH (HLR = 2-methylimidazol-4-yl-methylideneamino-R-(+)-1-methylphenyl)](/preview/png/10571860.png "First Page Preview: Chiral spin crossover iron(II) complex, fac-Î-[FeII(HLR)3](ClO4)2·EtOH (HLR = 2-methylimidazol-4-yl-methylideneamino-R-(+)-1-methylphenyl)")
Authors
Tomotaka Hashibe, Takeshi Fujinami, Daisuke Furusho, Naohide Matsumoto, Yukinari Sunatsuki,