| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 10571875 | Inorganica Chimica Acta | 2005 | 18 Pages |
Abstract
A systematic investigation of the CuCl2/Mebta (Mebta = 1-methylbenzotriazole) reaction system is described. Several complexes were isolated, namely [Cu2Cl4(Mebta)4] (1), [CuCl2(Mebta)2] (2), {[Cu2Cl4(Mebta)2]}n (3), [Cu4OCl6(Mebta)4] · 0.25H2O (4 · 0.25H2O) and [Cu2Cl2(Mebta)6](ClO4)2 (5), which were structurally characterized by single-crystal X-ray crystallography and studied by spectroscopic methods. Their magnetic studies showed ferromagnetic interactions. A new magneto-structural criterion was developed, governing the magnetic exchange coupling in bis(μ-chloro) copper(II) dimers.
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Konstantina Skorda, Theocharis C. Stamatatos, Anastasios P. Vafiadis, Alexandra T. Lithoxoidou, Aris Terzis, Spyros P. Perlepes, Jerzy Mrozinski, Catherine P. Raptopoulou, John C. Plakatouras, Evangelos G. Bakalbassis,