Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
10571877 | Inorganica Chimica Acta | 2005 | 11 Pages |
Abstract
Five luminescent coordination polymers [Ag2(dps)2](ClO4)2 · MeCN, [Ag2(dps)2(μ2-MeCN)(MeCN)](ClO4)2 · MeCN · H2O, [Zn(dps)(CH3COO)2, [Zn(dps)2(H2O)2](ClO4)2 · H2O and [Cu2I2(dps)2] (where dps  = 4,4â²-dipyridylsulfide) were prepared. Compound [Ag2(dps)2](ClO4)2 exhibits pseudo-supramolecular isomerism with different Agâ¯Ag, ÏâÏ, Agâ¯S and unusual Agâ¯(μ2-MeCN) supramolecular interactions. Both blue luminescent zinc compounds self-assembled into 3D structures of different topologies with intriguing C-Hâ¯O, Hâ¯O, and Nâ¯H bonds. The Cu(I) compound is a yellow luminescent 2D-network polymer.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Sebastian Muthu, Zheng Ni, Jagadese J. Vittal,