Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
10571894 | Inorganica Chimica Acta | 2005 | 33 Pages |
Abstract
Adducts of the form MX:dppx (1:1)(n), M = silver(I) or copper(I), X = simple (pseudo-) halide or oxy-anion, dppx=bis(diphenylphosphino)alkane, Ph2P(CH2)xPPh2, x = 3-6 have been synthesised and characterized by spectroscopy and X-ray crystal studies. Adducts are defined of two binuclear forms: (i) [dppxM(μ-X)2Mdppx], with each ligand chelating a single metal atom, and (ii) [M(μ-X)2(μ-(P-dppx-Pâ²))2Mâ²] where both ligands dppx and halides bridge the two metal atoms; a few adducts are defined as polymers, the ligands connecting M(μ-X)2Mâ² kernels, this motif persisting in all forms.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Effendy Effendy, Corrado Di Nicola, Mauro Fianchini, Claudio Pettinari, Brian W. Skelton, Neil Somers, Allan H. White,