| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 10572176 | Inorganica Chimica Acta | 2011 | 6 Pages |
Abstract
⺠The decomposition of Ir-nitrosothiol complexes produces NOâ, sulfenic acids and NO2â. ⺠Nitrous oxide (N2O) and nitrogen were detected in the gas phase. ⺠Free nitroxyl (HNO) is proposed as an intermediate. ⺠The decomposition involves attack of H2O on the S atom of the coordinated nitrosothiol. ⺠The decomposition occurs through a different mechanism than for free nitrosothiols.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Daniel Kazhdan, Laura L. Perissinotti, Bernardo Watanabe, Marcos N. Eberlin, Humberto M.S. Milagre, Boniek G. Vaz, Dario A. Estrin, Fabio Doctorovich,