Article ID Journal Published Year Pages File Type
10572177 Inorganica Chimica Acta 2011 7 Pages PDF
Abstract
► The iron(II) clathrochelate with two inherent NH2-groups was obtained. ► Clathrochelate NH2-groups have an amide character and undergo deprotonation. ► The clathrochelate dianion is an acido-ligand and coordinates to copper(II) ion. ► The condensation of clathrochelate dianion with benzil gave piperazinone fragment. ► The reaction is benzilic-type rearrangement with 1,2-shift of the phenyl substituent.
Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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