| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 10572204 | Inorganica Chimica Acta | 2011 | 7 Pages |
Abstract
⺠We synthesized four Brâ complexes [FeIIH3LMe]Br·Y for comparing with Clâ analogues. ⺠Only [FeIIH3LMe]Br·CF3SO3 is isomorphous of related Clâ complex. ⺠[FeIIH3LMe]Br·CF3SO3 shows abrupt SCO with hysteresis, frozen-in and LIESST effects. ⺠At 296 and 93 K, CF3SO3 complex has a same NHâ¯Brâ hydrogen bonded layered assembly. ⺠The complexes with Yâ (PF6-,AsF6-,SbF6-) contain one methanol and show no SCO.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
![Layered iron(II) spin crossover complex constructed by NHâ¯Brâ hydrogen bonds with 2 K wide thermal hysteresis, [FeIIH3LMe]Br·CF3SO3 (H3LMe = tris[2-(((2-methylimidazol-4-yl)methylidene)amino)ethyl]amine)](/preview/png/10572204.png "First Page Preview: Layered iron(II) spin crossover complex constructed by NHâ¯Brâ hydrogen bonds with 2 K wide thermal hysteresis, [FeIIH3LMe]Br·CF3SO3 (H3LMe = tris[2-(((2-methylimidazol-4-yl)methylidene)amino)ethyl]amine)")
Authors
Hiroaki Hagiwara, Naohide Matsumoto, Seiichiro Iijima, Masaaki Kojima,