Article ID Journal Published Year Pages File Type
10572212 Inorganica Chimica Acta 2011 7 Pages PDF
Abstract
► [CpCr(CO)3]2 (1) undergoes facile reaction with an equivalent of Woollins' Reagent at ambient temperature. ► The ring-opening reaction of Woollins' Reagent was initiated via homolytic P-Se bond cleavage by CpCr(CO)n· (n = 2 (2A) or 3 (1A)). ► The ease of fragmentation of the P-Se heterocyclic ligand which leads to ring opening in Woollins' Reagent resembles well with its P-S analogue, Lawesson's Reagent.
Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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