Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
10572212 | Inorganica Chimica Acta | 2011 | 7 Pages |
Abstract
⺠[CpCr(CO)3]2 (1) undergoes facile reaction with an equivalent of Woollins' Reagent at ambient temperature. ⺠The ring-opening reaction of Woollins' Reagent was initiated via homolytic P-Se bond cleavage by CpCr(CO)n· (n = 2 (2A) or 3 (1A)). ⺠The ease of fragmentation of the P-Se heterocyclic ligand which leads to ring opening in Woollins' Reagent resembles well with its P-S analogue, Lawesson's Reagent.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Richard C.S. Wong, Mei Lee Ooi,