Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
10572227 | Inorganica Chimica Acta | 2005 | 7 Pages |
Abstract
The synthesis of heterobimetallic (TiCu, TiAg) and tetranuclear heterobimetallic (Ti2Ag2) transition metal complexes based on the organometallic Ï-tweezer building blocks [Ti](CCSiMe3)2 is described. In [{[Ti](μ-Ï,Ï-CCSiMe3)2}M-LL]+ and [{[Ti](μ-Ï,Ï-CCSiMe3)2}MLLM{(Me3SiCC-μ-Ï,Ï)2[Ti]}]2+ (M = Cu, Ag; LL = pyrazine- or pyridine-based bridging units) the metal containing parts are spanned by Ï-conjugated organic bridges LL. Depending on the nature of LL coordination polymers are also accessible.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
M. Al-Anber, Th. Stein, S. Vatsadze, H. Lang,