| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 10572244 | Inorganica Chimica Acta | 2005 | 5 Pages |
Abstract
The dimethylaminopyridine (DMAP) promotes the reaction between [Os(bpy)2(CO)(OTf)]OTf (1) (where OTf=CF3SO3-) and methylene chloride leading to [Os(bpy)2(CO)(Cl)]OTf (2). The reactivity and redox properties of 1 were investigated by means of room- and low-temperature electrochemical experiments in CH2Cl2.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
![Electrochemical behaviour and reactivity of [Os(bpy)2(CO)(OTf)]+ in halogenated solvents](/preview/png/10572244.png "First Page Preview: Electrochemical behaviour and reactivity of [Os(bpy)2(CO)(OTf)]+ in halogenated solvents")
Authors
Claudio Garino, Roberto Gobetto, Carlo Nervi, Luca Salassa,