| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 10572569 | Inorganica Chimica Acta | 2011 | 9 Pages |
Abstract
⺠The electronic structure of dipyrido[3,2-a:2â²,3â²-c]phenazine complexes is influenced by the presence of two close lying MOs (b1(Ï) and b1(phz)). ⺠Complexes have both MLCT and IL states that lie close in energy. ⺠Assignment of these states may be determined through time-resolved resonance Raman or infrared measurements. ⺠Time-resolved infrared measurements provide less ambiguous data for complexes with {Re(CO)3(R)}+ than Raman. ⺠Ultrafast time-resolved infrared measurements reveal relaxation between MLCT and IL states that are dependent on substituents.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
![Excited state vibrational spectroscopy of metal complexes of dipyrido[3,2-a:2â²,3â²-c]phenazine](/preview/png/10572569.png "First Page Preview: Excited state vibrational spectroscopy of metal complexes of dipyrido[3,2-a:2â²,3â²-c]phenazine")
Authors
Raphael Horvath, Keith C. Gordon,