Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
10572575 | Inorganica Chimica Acta | 2011 | 10 Pages |
Abstract
⺠Platinum complexes of methimazole (2-mercapto-1-ethylimidazole) coordinated in both thione and thiolate forms have been isolated and characterized. ⺠Molecular structure of [Pt(bipy)(HImS)2]Cl2 3H2O (3a 3H2O) has been established by single crystal X-ray crystallography. ⺠Platinum thiolate complex, [Pt(ImS)2(HImS)2] (5), yielded polynuclear platinum complexes which were studied by various techniques. ⺠The effect of diimine ligands on oxidation of methimazole moiety in the complexes has been studied by electrochemical oxidation and pulse radiolysis.
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Authors
Liladhar B. Kumbhare, Umang Singh, Beena G. Singh, Amey Wadawale, G. Kedarnath, Sanjio S. Zade, K. Indira Priyadarsini, Vimal K. Jain,