Article ID Journal Published Year Pages File Type
10572575 Inorganica Chimica Acta 2011 10 Pages PDF
Abstract
► Platinum complexes of methimazole (2-mercapto-1-ethylimidazole) coordinated in both thione and thiolate forms have been isolated and characterized. ► Molecular structure of [Pt(bipy)(HImS)2]Cl2 3H2O (3a 3H2O) has been established by single crystal X-ray crystallography. ► Platinum thiolate complex, [Pt(ImS)2(HImS)2] (5), yielded polynuclear platinum complexes which were studied by various techniques. ► The effect of diimine ligands on oxidation of methimazole moiety in the complexes has been studied by electrochemical oxidation and pulse radiolysis.
Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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