Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
10572578 | Inorganica Chimica Acta | 2011 | 10 Pages |
Abstract
⺠Novel mono- and bisphosphinite (-)-pinane-based ligands have been synthesized from (-)-α-pinene. ⺠Mixed with [(COD)2Rh]+[BF4]-, they displayed moderate up to high catalytic activity in hydrogenation of dimethyl itaconate. ⺠Complete hydrogenation of dimethyl itaconate with monophosphinite ligands has been carried out in MeOH at room temperature or 40 °C.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Dennis HobuÃ, Jens Hasenjäger, Birgit Driessen-Hölscher, Angelika Baro, Kirill V. Axenov, Sabine Laschat, Wolfgang Frey,