Article ID Journal Published Year Pages File Type
10572578 Inorganica Chimica Acta 2011 10 Pages PDF
Abstract
► Novel mono- and bisphosphinite (-)-pinane-based ligands have been synthesized from (-)-α-pinene. ► Mixed with [(COD)2Rh]+[BF4]-, they displayed moderate up to high catalytic activity in hydrogenation of dimethyl itaconate. ► Complete hydrogenation of dimethyl itaconate with monophosphinite ligands has been carried out in MeOH at room temperature or 40 °C.
Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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