| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 10572585 | Inorganica Chimica Acta | 2011 | 5 Pages |
Abstract
⺠Axial EPR signal observed for pentaammineurthenium(III) complexes of phenylcyanamide ligands. ⺠1H NMR chemical shifts are consistent with spin density largely localized on Ru. ⺠Gas-phase DFT and DFT/PCM spin density calculations place too much spin density on the phenylcyanamide ligand. ⺠Solvent donor-acceptor interactions stabilize the Ru(III) oxidation state.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Lubna Mahmoud, Serge I. Gorelsky, Wolfgang Kaim, Biprajit Sarkar, Robert J. Crutchley,