Article ID Journal Published Year Pages File Type
10572585 Inorganica Chimica Acta 2011 5 Pages PDF
Abstract
► Axial EPR signal observed for pentaammineurthenium(III) complexes of phenylcyanamide ligands. ► 1H NMR chemical shifts are consistent with spin density largely localized on Ru. ► Gas-phase DFT and DFT/PCM spin density calculations place too much spin density on the phenylcyanamide ligand. ► Solvent donor-acceptor interactions stabilize the Ru(III) oxidation state.
Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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