Article ID Journal Published Year Pages File Type
10572609 Inorganica Chimica Acta 2011 9 Pages PDF
Abstract
► New C3- symmetric phloroglucinol-based bridging ligands. ► Trinuclear complexes with paramagnetic octahedral high-spin nickel(II) ions. ► Weak antiferromagnetic exchange interactions are observed through the bridging ligands. ► Rather large zero-field splitting is observed for the nickel(II) ions. ► Competitive spin-polarization and superexchange mechanisms are observed, with the latter prevailing.
Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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