| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 10572619 | Inorganica Chimica Acta | 2011 | 6 Pages |
Abstract
⺠A metathetical approach allows the synthesis of calcium-based superbases. ⺠Calcium-based Hauser bases undergo immediate ligand exchange yielding homoleptic derivatives. ⺠Structures of calcium bis(amides) are dominated by electrostatic and steric factors. ⺠In dimeric dialkylamido calcium iodide the smaller anion occupies the bridging position.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
![N,N,Nâ²,Nâ²-Tetramethylethylendiamine adducts of amido calcium bases - Synthesis of monomeric [(tmeda)Ca{N(SiMe3)2}2], [(tmeda)Ca{NiPr2}2], and dimeric Hauser base-type [(tmeda)Ca(tmp)(μ-I)]2 (tmp = 2,2,6,6-tetramethylpiperidide)](/preview/png/10572619.png "First Page Preview: N,N,Nâ²,Nâ²-Tetramethylethylendiamine adducts of amido calcium bases - Synthesis of monomeric [(tmeda)Ca{N(SiMe3)2}2], [(tmeda)Ca{NiPr2}2], and dimeric Hauser base-type [(tmeda)Ca(tmp)(μ-I)]2 (tmp = 2,2,6,6-tetramethylpiperidide)")
Authors
Carsten Glock, Helmar Görls, Matthias Westerhausen,