Article ID Journal Published Year Pages File Type
10572653 Inorganica Chimica Acta 2005 8 Pages PDF
Abstract
We described the synthesis of dinuclear bis(diphenylphosphano)acetylene gold(I) and gold(III) derivatives. The luminescent dicoordinated chloro gold(I) complex displays an infinite twisted chain by intermolecular gold-gold interactions. The non-emissive tetracoordinated chloro gold(I) complex forms a cage with two gold centres at the apical positions bridged by three rigid diphosphane ligands.
Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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