Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
10572653 | Inorganica Chimica Acta | 2005 | 8 Pages |
Abstract
We described the synthesis of dinuclear bis(diphenylphosphano)acetylene gold(I) and gold(III) derivatives. The luminescent dicoordinated chloro gold(I) complex displays an infinite twisted chain by intermolecular gold-gold interactions. The non-emissive tetracoordinated chloro gold(I) complex forms a cage with two gold centres at the apical positions bridged by three rigid diphosphane ligands.
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Manuel BardajıÌ, M. Teresa de la Cruz, Peter G. Jones, Antonio Laguna, Julia MartıÌnez, M. Dolores Villacampa,