| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 10572659 | Inorganica Chimica Acta | 2005 | 13 Pages |
Abstract
The chlorodimethylsilyl ligands in Os(SiMe2Cl)Cl(CO)(PPh3)2 and Os(SiMe2Cl)(κ2-S2CNMe2)(CO)(PPh3)2 undergo hydrolysis to Os(SiMe2OH)Cl(CO)(PPh3)2 and Os(SiMe2OH)(κ2-S2CNMe2)(CO)(PPh3)2, respectively, which in turn can be deprotonated by tBuLi to give silanolate complexes which react with Me3 SiCl and Me3SnCl to give osmadisiloxane and osmastannasiloxane complexes.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Markus Albrecht, Wai-Him Kwok, Guo-Liang Lu, Clifton E.F. Rickard, Warren R. Roper, David M. Salter, L. James Wright,