Article ID Journal Published Year Pages File Type
10572660 Inorganica Chimica Acta 2005 9 Pages PDF
Abstract
1,3,2-Diazabora-[3]ferrocenophanes bearing various functionalities at the boron atom are readily accessible by the reaction of the dilithiated 1,1′-bis(trimethylsilylamino)ferrocene with boron halides. Strong endocyclic BN(pp)π interactions are indicated by an essentially planar arrangement of the atoms Fe, C1, N1, B, N2 and C1′, as shown by X-ray analysis and NMR spectroscopy.
Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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