| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 10572664 | Inorganica Chimica Acta | 2005 | 16 Pages |
Abstract
The new diiron alkynyl methoxy carbene complexes [Fe2{μ-CN(Me)(R)}(μ-CO)(CO){C(OMe)CCRâ²}(Cp)2]+ have been obtained following the traditional “Fischer synthesis”. These add amines selectively at the CC triple bond affording dinuclear species containing an enamino methoxy carbene ligand. When a proton is present on the enamino nitrogen, this can be reversibly removed to give a neutral vinyl imine complex.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Luigi Busetto, Fabio Marchetti, Stefano Zacchini, Valerio Zanotti,