| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 10572667 | Inorganica Chimica Acta | 2005 | 9 Pages |
Abstract
B-Chlorocatecholborane oxidatively adds to M(PR3)3Cl (MÂ =Â Rh, RÂ =Â Me; MÂ =Â Ir, RÂ =Â Me, Et) yielding six-coordinate mer,cis- (PR3)3Cl2M(BO2C6H4) complexes whereas reaction with B-bromocatecholborane gives a mixture of homo- and heterodihalides (PR3)3X1X2M(BO2C6H4) (X1, X2Â =Â Cl, Br), the disproportionation probably involving formation of a heteronuclear halide bridged intermediate.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Fábio E.S. Souza, Paul Nguyen, Todd B. Marder, Andrew J. Scott, William Clegg,