Article ID Journal Published Year Pages File Type
10572668 Inorganica Chimica Acta 2005 11 Pages PDF
Abstract
A series of π-indenylruthenium(II) compounds of the general composition [(η5-C9H7)Ru(L)(PPh3)X] including those where L is a carbene CRR′ has been prepared with [(η5-C9H7)Ru(η3-2-MeC3H4)(PPh3)] as the starting material. The respective carbene complexes react with C-nucleophiles such as MeLi, PhLi and CH2CHMgBr by C-C coupling to give hydrido(olefin), η3-allyl and η3-benzyl ruthenium(II) derivatives.
Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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