Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
10572668 | Inorganica Chimica Acta | 2005 | 11 Pages |
Abstract
A series of Ï-indenylruthenium(II) compounds of the general composition [(η5-C9H7)Ru(L)(PPh3)X] including those where L is a carbene CRRâ² has been prepared with [(η5-C9H7)Ru(η3-2-MeC3H4)(PPh3)] as the starting material. The respective carbene complexes react with C-nucleophiles such as MeLi, PhLi and CH2CHMgBr by C-C coupling to give hydrido(olefin), η3-allyl and η3-benzyl ruthenium(II) derivatives.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Helmut Werner, Gerhard Münch, Matthias Laubender,