Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
10572676 | Inorganica Chimica Acta | 2005 | 9 Pages |
Abstract
The reactions of [M(CC6H2Me3-2,4,6)X(CO)2(L)2] (M = Mo, W; X = Cl, Br; L = pyridine, 3,5-dimethylpyrazole) with Na[H2B(mt)2] (mt = methimazolyl) are metal dependent, providing either the alkylidyne complex [Mo(CC6H2Me3-2,4,6)(CO)2{κ3-H,S,Sâ²-H2B(mt)2}] or the bis(chelate) complex [W(CO){κ2-S,Sâ²-H2B(mt)2}{κ3-H,S,Sâ²-H2B(mt)2}], the latter featuring both bi and tridentate coordination modes for the H2B(mt)2 ligand.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Robyn J. Abernethy, Anthony F.Hill Anthony F.Hill, Horst Neumann, Anthony C. Willis,