| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 10572680 | Inorganica Chimica Acta | 2005 | 12 Pages |
Abstract
Ammonia and primary amines do not react with [(CO)5CrCCC(NMe2)Ph] by addition to the C1C2 bond of the allenylidene ligand but rather by replacement of the NMe2 substituent thus affording a convenient access to various amino-substituted allenylidene complexes. Usually, the Z isomer (with respect to the partial C3-N double bond) is formed exclusively.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Normen Szesni, Bernhard Weibert, Helmut Fischer,