Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
10572684 | Inorganica Chimica Acta | 2005 | 9 Pages |
Abstract
Protonation of diazadienes (DAD) with [H(OEt2)2][H2N{B(C6F5)3}2] gives salts of the extremely weakly coordinating amido-diborate anion, [DADH][H2N{B(C6F5)3}2], which show inter-ionic NHâ¯F hydrogen bonding in the solid state. The compounds react with zink alkyls and amides to give three- and four-coordinate complexes such as [{(PriDAD)Zn(μ-OH)}2][H2N{B(C6F5)3}2]2 and [(Ph*DAD)ZnR][H2N{B(C6F5)3}2] [R = Me, N(SiMe3)2; Ph*DAD = (MeCNC6H3Ph2-2,6)2]. Here, too, inter-ionic hydrogen bonding to organic fluorine atoms is an important structural element.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Mark D. Hannant, Mark Schormann, David L. Hughes, Manfred Bochmann,