| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 10572803 | Journal of Fluorine Chemistry | 2005 | 5 Pages |
Abstract
The synthesis of 1,1-difluoro-2-(dideuteriomethylene)-cyclopropane is reported along with the kinetics of its competing, reversible, first order rearrangements: (a) the degenerate rearrangement to 1,1-difluoro-3,3-dideuterio-2-methylene-cyclopropane, and (b) its rearrangement to 2,2-dideuterio-1-(difluoromethylene)-cyclopropane. The observed experimental ratio of these two rate constants, 2.3, is consistent with Borden's theoretically predicted ratio of 3.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
William R. Jr., Emilie Gautriaud, Xiaohong Cai,