| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 10572836 | Journal of Fluorine Chemistry | 2005 | 6 Pages |
Abstract
A fluoride-induced nucleophilic (phenylthio)difluoromethylation method using TMS-CF2SPh has been achieved. This new methodology efficiently transfers “PhSCF2” group into both enolizable and non-enolizable aldehydes and ketones to give corresponding (phenylthio)difluoromethylated alcohols in good to excellent yields.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
![Fluoride-induced nucleophilic (phenylthio)difluoromethylation of carbonyl compounds with [difluoro(phenylthio)methyl]trimethylsilane (TMS-CF2SPh)](/preview/png/10572836.png "First Page Preview: Fluoride-induced nucleophilic (phenylthio)difluoromethylation of carbonyl compounds with [difluoro(phenylthio)methyl]trimethylsilane (TMS-CF2SPh)")
Authors
G.K. Surya Prakash, Jinbo Hu, Ying Wang, George A. Olah,