Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
10572846 | Journal of Fluorine Chemistry | 2005 | 13 Pages |
Abstract
α,α-Difluoroacylsilanes were synthesised directly from a range of allyl ethers of trifluoroethanol via dehydrofluorination/metallation procedures, followed by thermal [3,3]-sigmatropic rearrangement of the intermediate vinylmetals. The scope and limitations of ether synthesis and dehydrofluorination/metallation are described.
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Christophe Audouard, Maxime R. Garayt, Erwan Kérourédan, Jonathan M. Percy, Hongli Yang,