| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 10574105 | Journal of Inorganic Biochemistry | 2005 | 4 Pages |
Abstract
This study presents a first MO analysis of the stereochemistry of cis-Mo(P)(NO)2, where the Mo(NO)2 unit eclipses a pair of opposite Mo-N bonds and also adopts a remarkable horseshoe-like conformation. In addition, we have uncovered a number of analogies - in terms of commonalities of metal-ligand orbital interactions - between the dinitrosylmetalloporphyrins, Fe(P)(NO)2 and Mo(P)(NO)2, and the two dialkylmetalloporphyrins, Ru(P)(CH3)2, and Zr(P)(CH3)2.
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Espen Tangen, Abhik Ghosh,