| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 10575068 | Journal of Organometallic Chemistry | 2005 | 7 Pages |
Abstract
Nucleophilic reactivity of organotin is enhanced by stoichiometric LiOH to give homoallyl and homopropargyl alcohols from allyl halide and arylepoxide under the aegis of catalytic Pd(0) and Pt(II). This 2-carbon extension strategy proceeds via tandem epoxide rearrangement-carbonyl addition and further reinforces earlier views on the enhanced reactivity of hydroxy derivatives of organotin such as RSnXn(OH)3 â n.
Related Topics
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Authors
Moloy Banerjee, Ujjal Kanti Roy, Pradipta Sinha, Sujit Roy,