| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 10575072 | Journal of Organometallic Chemistry | 2005 | 4 Pages |
Abstract
Blocking of the lone pair of electrons on the nitrogen atom in azaferrocene by coordination to the W(CO)5 moiety (as in complexes 1a-b) enables Friedel-Crafts acylation of this metallocene. The reaction occurs selectively at the cyclopentadienyl ligand in 10-50% yield. The X-ray structure of 2a was determined.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Konrad Kowalski, Janusz Zakrzewski, Lucjan Jerzykiewicz,