| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 10575081 | Journal of Organometallic Chemistry | 2005 | 7 Pages |
Abstract
The Pd(0)/Cu(I)-catalysed reactions between Co3(μ3-CBr)(CO)7(LL) [LL = (CO)2, μ-dppm] and HCCCC[MLn] [MLn = W(CO)3Cp or Ru(dppe)Cp*] give the C5 complexes {LnM}CCCCC{Co3(CO)9}. An attempt to prepare a C3 analogue from Ru(CCH)(PPh3)2Cp and Co3(μ3-CBr)(CO)9 gave instead the acyl derivative {Cp(Ph3P)2Ru}CCC(O)C{Co3(CO)8 PPh3}.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Michael I. Bruce, Kathy A. Kramarczuk, Natasha N. Zaitseva, Brian W. Skelton, Allan H. White,