| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 10575109 | Journal of Organometallic Chemistry | 2005 | 14 Pages |
Abstract
Syntheses and temperature dependent NMR studies of some methylmagnesium complexes with different O- and N-donors L (L = thf, diglyme, NEt3, tmeda, dabco, pmdta) give insight into the influence of the co-ligand L on the position of the Schlenk equilibrium showing that in thf the equilibrium I (pmdta = N,N,Nâ²,Nâ³,Nâ³-pentamethyldiethylenetriamine) lies completely on the left side.
Keywords
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Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
![Synthesis, characterization and Schlenk equilibrium studies of methylmagnesium compounds with O- and N-donor ligands - the unexpected behavior of [MgMeBr(pmdta)] (pmdta = N,N,Nâ²,Nâ³,Nâ³-pentamethyldiethylenetriamine)](/preview/png/10575109.png "First Page Preview: Synthesis, characterization and Schlenk equilibrium studies of methylmagnesium compounds with O- and N-donor ligands - the unexpected behavior of [MgMeBr(pmdta)] (pmdta = N,N,Nâ²,Nâ³,Nâ³-pentamethyldiethylenetriamine)")
Authors
Rushdi I. Yousef, Bernhard Walfort, Tobias Rüffer, Christoph Wagner, Harry Schmidt, Renate Herzog, Dirk Steinborn,