Article ID Journal Published Year Pages File Type
10575125 Journal of Organometallic Chemistry 2005 7 Pages PDF
Abstract
Ruthenium complexes with bipyridine-analogous quaternized (N,C)-bidentate ligands [RuL(bpy)2](PF6)2 (bpy = 2,2′-bipyridine, (1), L = N′-methyl-2,4′-bipyridinium; (2), L = N′-methyl-2,3′-bipyridinium) were synthesized and characterized. The NMR and electrochemical studies indicate that the C-coordinated ring of (N,C)-ligands in 1 and 2 are linked to ruthenium(II) with pyridinium and pyridinylidene manners, respectively.
Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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