| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 10575155 | Journal of Organometallic Chemistry | 2005 | 10 Pages |
Abstract
The reaction of [(η6-C6Me6)Ru(μ-Cl)Cl]21 with sodium azide in various concentrations generates versatile orange-colored dimeric complexes [{(η6-C6Me6)Ru(μ-N3)(N3)}2] 2 and [{(η6-C6Me6)Ru(μ-N3)(Cl)}2] 3. These compounds undergo a variety of substitution reactions with neutral ligands to afford mononuclear and binuclear bridged complexes.
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
P. Govindaswamy, Patrick J. Carroll, Yurij A. Mozharivskyj, Mohan Rao Kollipara,
![First Page Preview: Syntheses and characterization of [(η6-C6Me6)Ru(μ-N3)(X)]2 (X = N3 and Cl) complexes and their reactions towards mono- and bidentate ligands Syntheses and characterization of [(η6-C6Me6)Ru(μ-N3)(X)]2 (X = N3 and Cl) complexes and their reactions towards mono- and bidentate ligands](/preview/png/10575155.png)