Article ID Journal Published Year Pages File Type
10575173 Journal of Organometallic Chemistry 2005 12 Pages PDF
Abstract
The ruthenium(II)-cyclopentadienyl moiety in combination with various phosphine and amine ligands yields highly active catalysts for the isomerization of allylic alcohols to ketones. Kinetic studies and mechanistic aspects are reported. A 31P NMR study sheds light on the intriguing inhibitory effect of dienes.
Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
Authors
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