| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 10575179 | Journal of Organometallic Chemistry | 2005 | 20 Pages |
Abstract
Lithium amino-di-tert-butylsilanolate reacts with halosilanes to give 1-silylamino-1,3-siloxanes (1-7). The tetrakis(1-silylamino)siloxane thermally condenses yielding a spirocyclic six-membered ring (8). One six-membered ring of 8 forms a boat and the other has a twist conformation. Lithium salts of amino-disiloxanes form silylamino-silanolates or amido-disiloxanes.
Related Topics
Physical Sciences and Engineering
Chemistry
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Authors
Susanne Kliem, Uwe Klingebiel, Mathias Noltemeyer, Stefan Schmatz,