| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 10575189 | Journal of Organometallic Chemistry | 2005 | 7 Pages |
Abstract
The reaction of the ansa-meso-[C2H4(4,7-Me2Indenyl)2]ZrMe2 with B(C6F5)3 afforded, besides the expected ion-pair with outward MeB(C6F5)3- (a), a minor isomer (b, 4.3%) with the bulky methylborate anion in the inward site. Evidence of migration of MeB(C6F5)3- between the two sites and of B(C6F5)3 attack on the (inward) methyl site of a has been obtained.
Related Topics
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Authors
Daniela Maggioni, Tiziana Beringhelli, Giuseppe D'Alfonso, Luigi Resconi,