Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
10575193 | Journal of Organometallic Chemistry | 2005 | 4 Pages |
Abstract
Metathesis of Cp*(CO)3MoBr and NaW(CO)3Cp produced Cp*(CO)3Mo-W(CO)3Cp. Its solid state structure exhibits an anti-arrangement of the η5-cyclopentadienyl and the η5-pentamethyl-cyclopentadienyl ligands that also dictate the Mo-W bond length. This is the first time that an unsupported Mo-W single bond distance is reported.
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Thomas Straub, Matti Haukka, Martin Brunner, Ari M.P. Koskinen, Tapani A. Pakkanen,