Article ID Journal Published Year Pages File Type
10575200 Journal of Organometallic Chemistry 2005 9 Pages PDF
Abstract
Trinuclear compounds [tBu5M3(OC6H4O)2] [ (1), M = In (2)] were synthesised by the reaction of C6H4(OH)2 with tBu3M. The structure of intermediate products [tBu4In2(OC6H4OH)2 · 2Et2O] (3), [tBu3In2(OC6H4O)(OC6H4OH)] (4), [tBu3Ga2(OC6H4O)(OC6H4OH)] (5) and [tBu3Ga2(OC6H4O)(OC6H4OH)] (6) were determined. According to the structures of 3-6 a reaction pathway of 1,2-catechols with group 13 metal trialkyls was proposed.
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Physical Sciences and Engineering Chemistry Inorganic Chemistry
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