Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
10575339 | Journal of Organometallic Chemistry | 2005 | 6 Pages |
Abstract
The synthesis of three new ruthenium titanium half-sandwich bimetallic complexes (p-cymene)[(μ-η5:η1-C5H4(CH2)nPR2)TiX3]RuCl2 (n = 0, X = Cl, R = Ph (11); n = 2, X = OiPr, R = Ph (12); n = 2, X = OiPr, R = Cy (13)) has been achieved. The structure of 11, determined by X-ray diffraction, is reported here. These bimetallic complexes and a complementary series of ruthenium titanocene bimetallic complexes have been tested in catalytic cyclopropanation.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Jérôme Goux, Pierre Le Gendre, Philippe Richard, Claude Moïse,