Article ID Journal Published Year Pages File Type
10575339 Journal of Organometallic Chemistry 2005 6 Pages PDF
Abstract
The synthesis of three new ruthenium titanium half-sandwich bimetallic complexes (p-cymene)[(μ-η5:η1-C5H4(CH2)nPR2)TiX3]RuCl2 (n = 0, X = Cl, R = Ph (11); n = 2, X = OiPr, R = Ph (12); n = 2, X = OiPr, R = Cy (13)) has been achieved. The structure of 11, determined by X-ray diffraction, is reported here. These bimetallic complexes and a complementary series of ruthenium titanocene bimetallic complexes have been tested in catalytic cyclopropanation.
Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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